WebMar 26, 2024 · This paper investigates about the theoretical study on center and edge site interaction of carbon dioxide and water molecules with amine (NH 2)-, methyl (CH 3)-, … WebJan 1, 2024 · The nonlinear absorption coefficients of the four rare-earth phthalocyanines were LaPc (β = 1.86ⅹ10 −10 m/W), YPc (β = 9.78ⅹ10 −11 m/W), YbPc (β = 6.63ⅹ10 −11 m/W), ScPc (β = 7.43ⅹ10 −11 m/W), respectively, indicating that the degree of aggregation between phthalocyanine rings gradually increases as the radius of rare earth metals changes from …
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WebApr 5, 2010 · Visible-Light Photoexcited Electron Dynamics of Scandium Endohedral Metallofullerenes: The Cage Symmetry and Substituent Effects. Journal of the American Chemical Society 2015, 137 ... Silicon Phthalocyanine Covalently Functionalized N-Doped Ultrasmall Reduced Graphene Oxide Decorated with Pt Nanoparticles for Hydrogen … WebA series of new scandium complexes supported by the phthalocyanine (Pc) ligand have been prepared and structurally characterized. Reaction of ScCl 3 with phthalonitrile affords a mixture of PcScCl (1) and unreacted ScCl 3, which upon addition of LiCH(SiMe 3) 2 yields THF-soluble PcSc(μ-Cl 2)Li(THF) 2 (2). Metathesis with NaCp or LiCp∗ generates PcSc(η 5 … faa approved test administrators of trust
Crown-substituted Sc(III) phthalocyaninates: Synthesis and …
WebA known indium(III) phthalocyanine was also investigated to compare its optical limiting behavior with the Ge(IV) and Sn(IV) containing compounds. Ge(IV) and Sn(IV) phthalocyanines exhibit a better optical limiting performance in polymer matrices than in solution, which is interesting for practical applications. WebUnsymmetrical functionalization of phthalocyanines has opened a wide range of new applications of this type of aromatic compounds in materials science. ... Impact of functional groups substitution on the molecular properties of magnesium and scandium phthalocyanines. Agnes Lincy Arokiyanathan and Senthilkumar Lakshmipathi. 1 Nov 2024 ... WebAbstract: The preparation and structural characterization of a pair of scandium(III) phthalocyanine hydroxide complexes were achieved by reaction of PcScCl with alkali metal alkoxides, likely via hydrolysis of soluble PcSc-alkoxide intermediates. A Sc 2 Li 2 (μ 3-OH) 4 cubane supported by two distorted Pc rings of the form (PcSc) 2 (μ 3-OH) 4 Li 2 … faa approved schools for air traffic control